全文获取类型
收费全文 | 26049篇 |
免费 | 1699篇 |
国内免费 | 1590篇 |
专业分类
电工技术 | 520篇 |
技术理论 | 1篇 |
综合类 | 1272篇 |
化学工业 | 6667篇 |
金属工艺 | 7158篇 |
机械仪表 | 1423篇 |
建筑科学 | 1257篇 |
矿业工程 | 751篇 |
能源动力 | 560篇 |
轻工业 | 1515篇 |
水利工程 | 102篇 |
石油天然气 | 614篇 |
武器工业 | 233篇 |
无线电 | 1080篇 |
一般工业技术 | 4329篇 |
冶金工业 | 1237篇 |
原子能技术 | 144篇 |
自动化技术 | 475篇 |
出版年
2024年 | 92篇 |
2023年 | 515篇 |
2022年 | 743篇 |
2021年 | 835篇 |
2020年 | 767篇 |
2019年 | 750篇 |
2018年 | 743篇 |
2017年 | 953篇 |
2016年 | 821篇 |
2015年 | 862篇 |
2014年 | 1287篇 |
2013年 | 1384篇 |
2012年 | 1714篇 |
2011年 | 1970篇 |
2010年 | 1566篇 |
2009年 | 1548篇 |
2008年 | 1263篇 |
2007年 | 1615篇 |
2006年 | 1644篇 |
2005年 | 1364篇 |
2004年 | 1204篇 |
2003年 | 987篇 |
2002年 | 864篇 |
2001年 | 716篇 |
2000年 | 669篇 |
1999年 | 472篇 |
1998年 | 428篇 |
1997年 | 321篇 |
1996年 | 279篇 |
1995年 | 242篇 |
1994年 | 176篇 |
1993年 | 159篇 |
1992年 | 134篇 |
1991年 | 69篇 |
1990年 | 57篇 |
1989年 | 50篇 |
1988年 | 21篇 |
1987年 | 6篇 |
1986年 | 16篇 |
1985年 | 7篇 |
1984年 | 3篇 |
1983年 | 6篇 |
1982年 | 5篇 |
1981年 | 3篇 |
1980年 | 2篇 |
1976年 | 1篇 |
1959年 | 2篇 |
1951年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
21.
Xueliang Wang Huiqin Yin Wenguan Liu Guojun Yu Jian He Zhongfeng Tang Long Yan 《工业材料与腐蚀》2020,71(6):931-937
Understanding the corrosion of molten ZnCl2 on metal surfaces is significant for the corrosion protection of metals, sustainable use of molten salts, preparation of ZnO coatings, and so on. In this paper, surfaces of pure Ni, Cr, and Fe corroded by molten ZnCl2 were investigated. The results show that Ni suffered very slight corrosion, while Cr experienced more serious corrosion than Ni, but lighter corrosion than Fe. The morphology of the corrosion of Cr and Fe, respectively, presented pitting and intergranular corrosion characteristics. Furthermore, nanostructured ZnO coatings were obtained on the surfaces of Ni and Fe, but not on the surface of Cr. The ZnO coating on the Ni surface was doped with a small amount of Zn5(OH)8Cl2, and the ZnO coating on the Fe surface was doped with ZnFe2O4 and Zn2OCl2. The coatings on the Ni and Fe surfaces had an average thickness of 1.5 and 50 μm, respectively. 相似文献
22.
化学气相沉积钨涂层具有工艺简单、技术成熟度高、涂层综合质量优异等特点,广泛应用于国防、航天、核工业等领域。首先介绍了化学气相沉积钨涂层的原理和特点,重点讨论了化学气相沉积钨涂层的工艺及应用研究现状,包括化学气相沉积钨涂层微观组织控制工艺及在耐辐射、耐磨耐蚀和高温防护领域的应用,同时对新型化学气相沉积钨涂层技术的发展进行了展望。一是改善现有工艺存在的反应气源与反应产物毒性大等问题,满足绿色环保的发展要求;二是改善现有工艺存在的沉积温度高、沉积速率偏低等问题,实现在不同衬底表面的高效、高质量沉积;三是改善现有化学气相沉积钨涂层结构与功能单一等问题,满足构件对钨涂层高性能和多功能的需求。 相似文献
23.
24.
粉末渗锌工艺是一种热扩散表面改性技术,将渗锌剂与钢构件在高温条件下接触,利用原子扩散作用,在构件表面形成一层合金保护层。作为一种工艺简单、环境友好的高效表面防腐处理工艺,粉末渗锌技术可有效改善金属材料的耐磨、耐蚀和耐氧化等性能,具有广泛的应用前景而备受研究者的关注。首先分析了粉末渗锌层的形成机理,并重点讨论了渗层的组织结构;然后,综述了保温温度、保温时间以及合金元素等因素对渗层形成的影响。研究者发现,升高温度和延长时间有益于渗层厚度的增加,但要合理控制,温度过高或时间过长不仅使渗层性能变差,还会增加能耗和降低生产率。此外,通过调整渗剂中合金元素的添加量以及种类,能够改善渗锌层的性能,但各类元素的最佳添加量以及其对渗层的改性机理还有待于进一步探究。目前,粉末渗锌生产中存在效率低的问题,在渗锌工艺中应用机械能助渗技术和纳米技术,可有效提高渗锌效率、改善渗层性能。最后,结合当前的研究现状,对粉末渗锌工艺的研究方向进行了探讨。 相似文献
25.
Although Mg alloy possesses high specific strength, low density, and good biocompatibility, poor corrosion resistance hinders its further applications. In the present study, an innovative protective layer against corrosion was prepared on the AZ31 Mg alloy via alkali pretreatment followed by vanillic acid treatment. The alkali pretreatment supplied –OH for the AZ31 Mg alloy surface to react with vanillic acid. The vanillic acid treatment played a crucial role in enhancing the corrosion resistance due to the excellent ability to act as a barrier and retard aqueous solution penetration, which effectively isolated the underlying Mg alloy from the corrosive environment. The corrosion current density of alkali and vanillic acid-treated Mg alloy (AZ31V) almost showed two orders of magnitude lower values in comparison with that of the AZ31 Mg alloy, and the corrosion potential of AZ31V Mg alloy increased from −1.41 to −1.25 V. The immersion tests proved that there was no occurrence of severe corrosion. Hence, the alkali pretreatment and vanillic acid treatment may represent a promising method to improve the corrosion resistance of Mg alloy. 相似文献
26.
Rahul Sasidharan Pillai Matteo Frasnelli Vincenzo M. Sglavo 《Ceramics International》2018,44(2):1328-1333
The present work focuses on the fabrication of βTCP (β-tricalcium phosphate) and HA/βTCP (hydroxyapatite/β-tricalcium phosphate) composite coatings by plasma spraying. The starting powders were produced via solid-state method using 2 wt% MgO to stabilize βTCP phase. The synthesized powders were preliminarily granulated to be used by the plasma spray process. Coatings obtained on titanium substrates are uniform and well adherent but due to the high temperature and cooling rate typical for plasma spraying process, βTCP phase is almost totally transformed into the α allotrope. Thermal treatment at 800 °C allows the reconversion of the phase αTCP→ βTCP. It is therefore possible to produce coatings with tuneable dissolution properties by selecting the proper initial powder mixture and the specific thermal treatment. 相似文献
27.
油基钻井液的封堵性能研究与应用 总被引:7,自引:5,他引:2
在涠洲12-1北油田一期工程中使用油基钻井液后事故率明显降低,但仍未能彻底解决涠二段硬脆性泥页岩井壁稳定性问题。对进一步加强油基钻井液的封堵能力进行了室内研究。通过在油基钻井液中引入超微细颗粒材料、纤维材料、变形材料和粘弹性材料,可大幅度提高其封堵能力。在涠洲12-1北油田二期工程中应用了加强封堵能力的油基钻井液,结果钻井施工非常顺利,几乎无井下复杂事故。室内评价及二期工程实践结果表明,增强油基钻井液的封堵能力对保持硬脆性泥页岩井壁稳定至关重要。 相似文献
28.
29.
Ferrite particles coated with biocompatible phases can be used for hyperthermia treatment of cancer. We have synthesized substituted
calcium hexaferrite, which is not stable on its own but is stabilized with small substitution of La. Hexaferrite of chemical
composition (CaO)0.75(La203)0.20(Fe2O3)6 was prepared using citrate gel method. Hydroxyapatite was prepared by precipitating it from aqueous solution of Ca(NO3)2 and (NH4)2HPO4 maintaining pH above 11. Four different methods were used for coating of hydroxyapatite on ferrite particles. SEM with EDX
and X-ray diffraction analysis shows clear evidence of coating of hydroxyapatite on ferrite particles. These coated ferrite
particles exhibited coercive field up to 2 kOe, which could be made useful for hysteresis heating in hyperthermia. Studies
by culturing BHK-21 cells and WBC over the samples show evidence of biocompatibility. SEM micrographs and cell counts give
clear indication of cell growth on the surface of the sample. Finally coated ferrite particle was implanted in Kasaulli mouse
to test its biocompatibility. The magnetic properties and biocompatibility studies show that these hydroxyapatite coated ferrites
could be useful for hyperthermia. 相似文献
30.